Pradeep T

IIT MADRAS

Profile

Pradeep’s work is in the area of molecular materials and surfaces.
His group discovered that noble metal nanoparticles degrade halocarbons efficiently to amorphous carbon and metal halides at room temperature and at low concentrations. This discovery has led to the world’s first nanochemistry based water filter for pesticide removal as many pesticides of relevance are halocarbons. This technology is estimated to have reached about 9 million people. His group developed several technologies to remove other contaminants from drinking water. Combining several such materials, an all-inclusive affordable drinking water purifier has been developed. Exciting aspect of this technology is the creation of advanced materials by simple and environment-friendly methods. This technology, named AMRIT, is being implemented now in the arsenic affected regions of India. About one million people have been benefitted from these installations. Several other drinking water technologies have been rolled out from his lab. To take such technologies forward, four companies have been incubated with the participation of IIT Madras. This activity is now being expanded globally.
A large part of his recent research is on atomically precise clusters of noble metals. His group discovered several new clusters called quantum clusters or nanomolecules. These have been used for diverse applications ranging from luminescent labels to metal ion sensors. His group has shown that such small pieces of matter behave like simple molecules, in their chemical reactions between each other. To account for their unique properties, including reactions, a nomenclature system has been introduced. They are named as aspicules, meaning ’shielded molecules’.
His group discovered new methods to transform ions to novel materials. Several new phenomena have been discovered using such materials. His group introduced new methods to create ions in ambient air and developed mass spectrometric techniques using them.
His group studied the dynamics of monolayers in monolayer protected nanoparticles and showed that monolayers existed in a rotationally frozen state on nanoparticle surfaces. His group found a ’transverse electrokinetic effect’ in which a potential is generated on nanoparticle assemblies anchored on surfaces, when a liquid is flown over them. His group also discovered that in the presence of metal nanoparticles, single walled carbon nanotube (SWNT) bundles emit light in the visible region of the electromagnetic spectrum, irrespective of whether it is metallic or semi-conducting.
His group found that diffusion of chemically similar molecules through ultra thin ice films exhibits several surprises. A new structural transition on the top-most layers of ice surfaces has been discovered at low temperatures. His group showed that 1 eV proton collisions at water ice surfaces make dihydrogen cation. From all these, it is clear that ultra-low energy ion collisions at ice surfaces manifest several surprises. Very recently, his group showed that methane hydrate can be formed in extremely low pressure and low temperature conditions as in space.

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